Depends really. Most of them have great b-sides (i.e. "A Little Soul" and "Help the Aged") but they're also available on the deluxe editions of the albums, you might be better off buying them instead if it's b-sides you're after and don't own them already. If you want the original singles then I'd say that isn't too badly priced, they generally go out for about £3-£5 a piece.
Its seems a bit expensive to me. Unless you're a collector you would be better off just buying the singles with b-sides not on the deluxe editions. They are pretty cheap on Amazon, for example you can get a used Help The Aged for only 1p! This has Tomorrow Never Lies on it which is far superior to Tomorrow Never Dies on This Is Hardcore Deluxe.
The "Pulped" box-set is the worst mastering I have ever heard in my life. It sounds like the CDs have been taped onto cassette and back to CD. Anyone who doesn't believe me, just listen to an original or Fire reissue then "Pulped" or rip a track off both without normalisation and open it in a wav editor.